H2 S catalysed by CBS regulates testosterone synthesis through affecting the sulfhydrylation of PDE

J Cell Mol Med. 2021 Apr;25(7):3460-3468. doi: 10.1111/jcmm.16428. Epub 2021 Mar 13.

Abstract

Testosterone deficiency resulted in increased mortality in men. Our previous work found that hydrogen sulphide (H2 S) significantly alleviated the spermatogenesis disorder. To investigate whether H2 S could regulate testosterone synthesis and the relative signalling pathways. Disorder model of testosterone synthesis was constructed in vitro and in vivo. The cell viability was detected using CCK-8 method. The concentration of H2 S and testosterone were examined using ELISA kits. The relative mRNA and protein expression of CBS, PDE4A, PDE8A and proteins related to testosterone synthesis were detected by RT-qPCR and western blotting. PAS staining was used to detect the inflammatory status of testis. The sulfhydryl level of PDE4A and PDE8A was determined by Biotin Switch Technique. CBS overexpression inhibited while knockdown promoted LPS + H2 O2 induced injury in testosterone synthesis of MLTC-1 cells, though regulating the level of H2 S. The LPS + H2 O2 induced inhibition on cAMP and p-PKA was recovered by CBS overexpression, while addition of the specific inhibitor of PKA had opposite effects. CBS overexpression alleviated the inflammation status in testis and promoted the expression of StAR, P450scc, P450c17 and 3β-HSD. CBS could also exhibit its protective role through promoting sulfhydrylation of PDE4A and PDE8A. H2 S catalysed by CBS could recover testosterone synthesis in vitro and in vivo through inhibiting PDE expression via sulfhydryl modification and activating cAMP/PKA pathway.

Keywords: cAMP/PKA; cystathionine-β-synthase; hydrogen sulphide; phosphodiesterase; testosterone.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • 3',5'-Cyclic-AMP Phosphodiesterases / metabolism*
  • Animals
  • Cell Line, Tumor
  • Cell Survival / drug effects
  • Cyclic AMP / metabolism*
  • Cyclic Nucleotide Phosphodiesterases, Type 4 / metabolism*
  • Cystathionine beta-Synthase / metabolism*
  • Disease Models, Animal
  • HEK293 Cells
  • Humans
  • Hydrogen Sulfide / metabolism*
  • Hydrogen Sulfide / pharmacology
  • Male
  • Mice
  • Signal Transduction
  • Testis / metabolism
  • Testosterone / biosynthesis*
  • Testosterone / deficiency

Substances

  • Testosterone
  • Cyclic AMP
  • 3',5'-Cyclic-AMP Phosphodiesterases
  • Cyclic Nucleotide Phosphodiesterases, Type 4
  • Pde4a protein, mouse
  • Pde8a protein, mouse
  • Cystathionine beta-Synthase
  • Hydrogen Sulfide