This paper reports a general electrospinning method to prepare various metal phosphide/carbon nanofibers composite for electrochemical hydrogen evolution reaction (HER) catalysts. An earth-abundant organic acid-phytic acid is successfully incorporated into a conventional electrospinning precursor as the phosphorus source, and continuous nanofibers can be obtained through spinning. After heat treatment, metal phosphide/carbon composite nanofibers can be obtained, with fine phosphide nanoparticles well dispersed on the surface of an interconnected carbon backbone network. Such fibrous structures offer fast charge transfer pathways and enlarged active surface area, which are beneficial for electrocatalysts. As a result, enhance HER catalytic activity can be achieved.