An allenylidene Au(i) catalyst based on triazolylidene moieties, featuring the high σ-donating ability (comparable to that of other NHC ligands) and largely enhanced π-accepting ability of its ligand, was developed for the first time. As compared with the extant gold complexes such as IPrAuCl, Ph3PAuCl and (PhO)3PAuCl, these allenylidene Au(i) catalysts exhibited superior catalytic activities in the gold-catalyzed Nazarov reaction of aryl enones.