Bioassay of ferulic acid derivatives as influenza neuraminidase inhibitors

Arch Pharm (Weinheim). 2020 Jan;353(1):e1900174. doi: 10.1002/ardp.201900174. Epub 2019 Oct 28.

Abstract

Four series of ferulic acid derivatives were designed, synthesized, and evaluated for their neuraminidase (NA) inhibitory activities against influenza virus H1N1 in vitro. The pharmacological results showed that the majority of the target compounds exhibited moderate influenza NA inhibitory activity, which was also better than that of ferulic acid. The two most potent compounds were 1m and 4a with IC50 values of 12.77 ± 0.47 and 12.96 ± 1.34 μg/ml, respectively. On the basis of the biological results, a preliminary structure-activity relationship (SAR) was derived and discussed. Besides, molecular docking was performed to study the possible interactions of compounds 1p, 2d, 3b, and 4a with the active site of NA. It was found that the 4-OH-3-OMe group and the amide group (CON) of ferulic acid amide derivatives were two key pharmacophores for NA inhibitory activity. It is meaningful to further modify the natural product ferulic acid to improve its influenza NA inhibitory activity.

Keywords: ferulic acid derivatives; molecular docking; neuraminidase inhibitors.

MeSH terms

  • Antiviral Agents / chemical synthesis
  • Antiviral Agents / chemistry
  • Antiviral Agents / pharmacology*
  • Biological Assay*
  • Coumaric Acids / chemical synthesis
  • Coumaric Acids / chemistry
  • Coumaric Acids / pharmacology*
  • Crystallography, X-Ray
  • Dose-Response Relationship, Drug
  • Enzyme Inhibitors / chemical synthesis
  • Enzyme Inhibitors / chemistry
  • Enzyme Inhibitors / pharmacology*
  • Humans
  • Influenza A Virus, H1N1 Subtype / drug effects*
  • Influenza A Virus, H1N1 Subtype / enzymology
  • Microbial Sensitivity Tests
  • Models, Molecular
  • Molecular Structure
  • Neuraminidase / antagonists & inhibitors
  • Neuraminidase / metabolism
  • Structure-Activity Relationship

Substances

  • Antiviral Agents
  • Coumaric Acids
  • Enzyme Inhibitors
  • ferulic acid
  • Neuraminidase