Doxorubicin/cisplatin co-loaded hyaluronic acid/chitosan-based nanoparticles for in vitro synergistic combination chemotherapy of breast cancer

Carbohydr Polym. 2019 Dec 1:225:115206. doi: 10.1016/j.carbpol.2019.115206. Epub 2019 Aug 15.

Abstract

Combination chemotherapy has attracted more and more attention in the field of anticancer treatment. Herein, a synergetic targeted combination chemotherapy of doxorubicin (DOX) and cisplatin in breast cancer was realized by HER2 antibody-decorated nanoparticles assembled from aldehyde hyaluronic acid (AHA) and hydroxyethyl chitosan (HECS). Cisplatin and DOX were successively conjugated onto AHA through chelation and Schiff's base reaction, respectively, forming DOX/cisplatin-loaded AHA inner core. The core was sequentially complexed with HECS and targeting HER2 antibody-conjugated AHA. The formed near-spherical nanoplatform had an average size of ∼160 nm and a zeta potential of -28 mV and displayed pH-responsive surface charge reversal and drug release behaviors. HER2 receptor-mediated active targeting significantly enhanced the cellular uptake of nanoplatform. Importantly, DOX and cisplatin exhibited a synergistic cell-killing effect in human breast cancer MCF-7 cells. These results clearly indicate that the novel nanoplatform is promising for synergistic combination chemotherapy of breast cancer.

Keywords: Breast cancer; Combination chemotherapy; Self-assembly; Synergistic effect; Targeted delivery; pH-responsivity.

MeSH terms

  • Breast Neoplasms / drug therapy*
  • Chitosan / therapeutic use*
  • Cisplatin / administration & dosage
  • Doxorubicin / administration & dosage
  • Drug Carriers / therapeutic use
  • Drug Combinations
  • Drug Delivery Systems / methods*
  • Drug Liberation
  • Female
  • Humans
  • Hyaluronic Acid / therapeutic use*
  • MCF-7 Cells
  • Nanoparticles / therapeutic use*

Substances

  • Drug Carriers
  • Drug Combinations
  • Doxorubicin
  • Hyaluronic Acid
  • Chitosan
  • Cisplatin