pH dependence of the chirality of nematic cellulose nanocrystals

Sci Rep. 2019 Aug 5;9(1):11290. doi: 10.1038/s41598-019-47834-w.

Abstract

Cellulose nanocrystals produced by acid hydrolysis of native cellulose form a well-known chiral nematic liquid crystal phase. The mechanism involved in the formation of chirality has been the subject of a vigorous discussion. The pH and concentration dependence of the phase is studied using cellulose nanocrystal droplets within a silicon oil suspension, which allows for convenient real-time microscale manipulation of phase behaviors and properties. We demonstrate the existence of nematic phases at both low and high pH regions consistent with the Stroobants - Lekkerkerker - Odijk theory. Our results confirm electrostatic interactions play a critical role in controlling the strength of the chirality.

Publication types

  • Research Support, Non-U.S. Gov't