We investigate spin states of few electrons in a double quantum dot by coupling them to a magnetic field resilient NbTiN microwave resonator. The electric field of the resonator couples to the electric dipole moment of the charge states in the double dot. For a two-electron state the spin-triplet state has a vanishing electric dipole moment and can therefore be distinguished from the spin-singlet state. This way the charge dipole sensitivity of the resonator response is converted to a spin selectivity. We thereby investigate Pauli spin blockade known from transport experiments at finite source-drain bias. In addition we find an unconventional spin-blockade triggered by the absorption of resonator photons.