Hydrogen Confined in a Single Wall Carbon Nanotube Becomes a Metallic and Superconductive Nanowire under High Pressure

Nano Lett. 2019 Apr 10;19(4):2537-2542. doi: 10.1021/acs.nanolett.9b00258. Epub 2019 Mar 20.

Abstract

Metallic hydrogen is a long-desired material. However, the pressure needed to metallize hydrogen is difficult to access experimentally. We demonstrated that the high-density of hydrogen confined in a (8,0) single-wall carbon nanotube (SWNT) can be metallized at a relative low pressure of 163.5 GPa, due to the " physical compression" effect of SWNT. Through mimicking experimental measurements of the specific heat of confined hydrogen nanowire, we showed that the electronic specific heat of the hydrogen has a clear jump around 225 K, verifying a superconducting transition at this critical temperature. The superconducting hydrogen can be very well explained by the Eliashberg superconductivity theory for an electron-phonon strong-coupling system. Our simulation results open an avenue for the study of nanohydrogen materials at high pressure.

Keywords: Superconductivity; carbon nanotubes; electronic specific heat; hydrogen; physical compression.

Publication types

  • Research Support, Non-U.S. Gov't