Anthocyanins and metabolites resolve TNF-α-mediated production of E-selectin and adhesion of monocytes to endothelial cells

Chem Biol Interact. 2019 Feb 25:300:49-55. doi: 10.1016/j.cbi.2019.01.002. Epub 2019 Jan 3.

Abstract

This study investigated the capacity of an anthocyanin-rich fraction (ACN-RF) from blueberry, single anthocyanins (cyanidin, delphinidin and malvidin-3-glucoside; Cy, Dp and Mv-3-glc) and related metabolites (protocatechuic, gallic and syringic acid; PrA, GA and SA) to resolve an inflammation-driven adhesion of monocytes (THP-1) on endothelial cell (HUVECs) and secretion of cell adhesion molecules E-selectin and vascular cell adhesion molecule 1 (VCAM-1). The adhesion of THP-1 to HUVECs was induced by tumour necrosis factor α (TNF-α, 100 ng mL-1). Subsequently, ACN-RF, single ACNs and metabolites (from 0.01 to 10 μg mL-1) were incubated for 24 h. The adhesion was measured in a fluorescence spectrophotometer. E-selectin and VCAM-1 were quantified by ELISA. No toxicological effects were observed for the compounds and the doses tested. ACN-RF and Mv-3-glc reducedTHP-1 adhesion at all the concentrations with the maximum effect at 10 μg/ml (-60.2% for ACNs and-33.9% for Mv-3-glc). Cy-3-glc decreased the adhesion by about 41.8% at 10 μg mL-1, while PrA and GA reduced the adhesion of THP-1 to HUVECs both at 1 and at 10 μg mL-1 (-29.5% and -44.3% for PrA, respectively, and -18.0%and -59.3% for GA, respectively). At the same concentrations a significant reduction of E-selectin, but notVCAM-1 levels, was documented. No effect was observed following Dp-3-glc and SA supplementation. Overall, ACNs and metabolites seem to resolve, in a dose-dependent manner, the inflammation-driven adhesion of THP-1 to HUVECs by decreasing E-selectin concentrations. Interestingly, Mv-3-glc was active at physiologically relevant concentrations.

Keywords: Anthocyanins; Atherogenesis; Cell culture; E-selectin; Metabolites; VCAM-1.

MeSH terms

  • Anthocyanins / metabolism
  • Anthocyanins / pharmacology*
  • Cell Adhesion / drug effects
  • Cell Line
  • Cell Survival / drug effects
  • E-Selectin / analysis
  • E-Selectin / metabolism*
  • Glucosides / pharmacology
  • Human Umbilical Vein Endothelial Cells
  • Humans
  • Monocytes / cytology
  • Monocytes / metabolism
  • Tumor Necrosis Factor-alpha / pharmacology*
  • Vascular Cell Adhesion Molecule-1 / analysis
  • Vascular Cell Adhesion Molecule-1 / metabolism

Substances

  • Anthocyanins
  • E-Selectin
  • Glucosides
  • Tumor Necrosis Factor-alpha
  • Vascular Cell Adhesion Molecule-1
  • malvidin-3-glucoside