Prussian blue coupled with zinc oxide has been synthesized via a facial heat treatment process. As a cathode for sodium ion batteries, the PB coupled with ZnO delivers an excellent rate performance, retaining 86.2 mA h g-1 at 10 A g-1 and a high reversible capacity of 89.9 mA h g-1 at 0.2 A g-1 after 500 cycles.