Preparation of ionic liquid hybrid melamine-based covalent organic polymer functionalized polymer monolithic material for the preconcentration of synthetic phenolic antioxidants

Abstract

In this study, a hybrid composite containing melamine-based covalent organic polymer (MCOP) and ionic liquid (IL) was designed and employed for the functionalization of polymer monolith. The obtained polymer monolithic material was confirmed by scanning electron microscopy, Fourier-transformed infrared spectroscopy, X-ray photoelectron spectroscopy, and thermal gravimetric analysis. A polymer monolith microextraction (PMME) strategy was established based on the monolith for the enrichment of synthetic phenolic antioxidants, exhibiting high sensitivity, good stability and repeatability. Intra-day and inter-day relative standard deviations were both less than 10%. The developed PMME-HPLC method was applied to the preconcentration and determination of synthetic phenolic antioxidants in cosmetic samples and assessed through recovery studies. The developed polymer monolithic material had great potential as a candidate in the preconcentration field for PMME.

Keywords: Ionic liquid; Melamine-based covalent organic polymer; Polymer monolith; Synthetic phenolic antioxidants.