Bronsted Acid/Organic Photoredox Cooperative Catalysis: Easy Access to Tri- and Tetrasubstituted Alkenylphosphorus Compounds from Alcohols and P-H Species

Peizhong Xie; Jing Fan; Yanan Liu; Xiangyang Wo; Weishan Fu; Teck-Peng Loh

doi:10.1021/acs.orglett.8b01173

Bronsted Acid/Organic Photoredox Cooperative Catalysis: Easy Access to Tri- and Tetrasubstituted Alkenylphosphorus Compounds from Alcohols and P-H Species

Org Lett. 2018 Jun 1;20(11):3341-3344. doi: 10.1021/acs.orglett.8b01173. Epub 2018 May 21.

Authors

Peizhong Xie¹, Jing Fan¹, Yanan Liu¹, Xiangyang Wo¹, Weishan Fu¹, Teck-Peng Loh^{1

2

3}

Affiliations

¹ School of Chemistry and Molecular Engineering, Institute of Advanced Synthesis, Jiangsu National Synergetic Innovation Center for Advanced Materials , Nanjing Tech University , Nanjing 211816 , P. R. China.
² Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences , Nanyang Technological University , Singapore 637371.
³ Department of Chemistry , University of Science and Technology of China , Hefei , Anhui 230026 , P. R. China.

PMID: 29781271
DOI: 10.1021/acs.orglett.8b01173

Abstract

A Bronsted acid/organic photoredox cooperative catalytic system toward P-C bond formation from alcohols and P-H species is developed. With the assistance of visible light and TBHP, the reactions proceeded smoothly in an environmentally benign manner to give various alkenylphosphorus compounds in high efficiency.

Publication types

Research Support, Non-U.S. Gov't