Iron-Sulfur Clusters in Zinc Finger Proteins

Methods Enzymol. 2018:599:101-137. doi: 10.1016/bs.mie.2017.09.005. Epub 2018 Jan 5.

Abstract

Zinc finger (ZF) proteins are proteins that use zinc as a structural cofactor. The common feature among all ZFs is that they contain repeats of four cysteine and/or histidine residues within their primary amino acid sequence. With the explosion of genome sequencing in the early 2000s, a large number of proteins were annotated as ZFs based solely upon amino acid sequence. As these proteins began to be characterized experimentally, it was discovered that some of these proteins contain iron-sulfur sites either in place of or in addition to zinc. Here, we describe methods to isolate and characterize one such ZF protein, cleavage and polyadenylation specificity factor 30 (CPSF3O) with respect to its metal-loading and RNA-binding activity.

Keywords: CPSF30; Electrophoretic mobility shift assay; Fluorescence anisotropy; Inductively coupled plasma mass spectrometry; Iron–sulfur cluster; RNA; Size exclusion chromatography; X-ray absorption spectroscopy; Zinc finger; [2Fe–2S].

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Animals
  • Chromatography, Gel / methods
  • Cleavage And Polyadenylation Specificity Factor / chemistry*
  • Cleavage And Polyadenylation Specificity Factor / genetics
  • Cleavage And Polyadenylation Specificity Factor / isolation & purification
  • Cleavage And Polyadenylation Specificity Factor / metabolism*
  • Cloning, Molecular / methods
  • Electrophoretic Mobility Shift Assay / methods
  • Escherichia coli / genetics
  • Fluorescence Polarization / methods
  • Humans
  • Iron-Sulfur Proteins / chemistry
  • Iron-Sulfur Proteins / genetics
  • Iron-Sulfur Proteins / isolation & purification
  • Iron-Sulfur Proteins / metabolism
  • Mass Spectrometry / methods
  • Models, Molecular
  • RNA / metabolism*
  • X-Ray Absorption Spectroscopy / methods
  • Zinc Fingers*

Substances

  • CPSF4 protein, human
  • Cleavage And Polyadenylation Specificity Factor
  • Iron-Sulfur Proteins
  • RNA