Spontaneous formation of a chiral (Mo2O2S2)2+-based cluster driven by dimeric {Te2O6}-based templates

Jamie W Purcell; De-Liang Long; Edward C Lee; Leroy Cronin; Haralampos N Miras

doi:10.1039/c8dt00832a

Spontaneous formation of a chiral (Mo₂O₂S₂)²⁺-based cluster driven by dimeric {Te₂O₆}-based templates

Dalton Trans. 2018 May 8;47(18):6283-6287. doi: 10.1039/c8dt00832a.

Authors

Jamie W Purcell¹, De-Liang Long, Edward C Lee, Leroy Cronin, Haralampos N Miras

Affiliation

¹ WestCHEM, School of Chemistry, University of Glasgow, Glasgow, G12 8QQ, UK. Charalampos.moiras@glasgow.ac.uk Lee.cronin@glasgow.ac.uk.

Abstract

Utilization of [Mo2S2O2(H2O)6]2+ and a tellurite anion led to the formation of three new clusters, 1-3, with unique structural features. The tellurite anion not only templated the formation of [(Mo2O2S2)4(TeO3)(OH)9]3-1 and [(Mo2O2S2)12(TeO3)4(TeO4)2 (OH)18]10-3, but also the in situ generation of two different types of dimeric {Te2O6} based moieties induced the spontaneous assembly of the chiral [(Mo2O2S2)10(TeO3)(Te2O6)2(OH)18]8- anionic cluster, 2.