Optimizing the preparation and stability of decorated antiretroviral drug nanocrystals

Nanomedicine (Lond). 2018 Apr;13(8):871-885. doi: 10.2217/nnm-2017-0381. Epub 2018 Mar 19.

Abstract

Aim: While the therapeutic potential for current long-acting (LA) antiretroviral therapy (ART) is undeniable, ligand-decorated nanoformulated LA-ART could optimize drug delivery to viral reservoirs. The development of decorated ART hinges, however, on formulation processes and manufacture efficiencies. To this end, we compared manufacture and purification techniques for ligand-decorated antiretroviral drug nanocrystals.

Materials & methods: Ligand-decorated nanoparticle manufacturing was tested using folic acid (FA) nanoformulated cabotegravir.

Results: Direct manufacturing of FA-cabotegravir resulted in stable particles with high drug loading and monocyte-macrophage targeting. A one step 'direct' scheme proved superior over differential centrifugation or tangential flow filtration facilitating particle stability and preparation simplicity and efficiency.

Conclusion: Direct manufacturing of FA nanoparticles provides a path toward large-scale clinical grade manufacturing of cell-targeted LA-ART.

Keywords: cabotegravir; long-acting antiretrovirals; monocyte-derived macrophage; nanocrystals; uptake and release.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Anti-Retroviral Agents / administration & dosage*
  • Anti-Retroviral Agents / chemistry
  • Disease Models, Animal
  • Drug Delivery Systems*
  • Folic Acid / administration & dosage
  • Folic Acid / chemistry
  • HIV Infections / drug therapy*
  • HIV Infections / virology
  • HIV-1 / drug effects
  • HIV-1 / pathogenicity
  • Humans
  • Macrophages / drug effects
  • Mice
  • Nanoparticles / administration & dosage*
  • Nanoparticles / chemistry
  • Pyridones / administration & dosage
  • Pyridones / chemistry
  • Tissue Distribution / drug effects

Substances

  • Anti-Retroviral Agents
  • Pyridones
  • Folic Acid
  • cabotegravir