A microporous MOF with open metal sites and Lewis basic sites for selective CO2 capture

Jinjie Qian; Qipeng Li; Linfeng Liang; Ting-Ting Li; Yue Hu; Shaoming Huang

doi:10.1039/c7dt03255b

A microporous MOF with open metal sites and Lewis basic sites for selective CO₂ capture

Dalton Trans. 2017 Oct 24;46(41):14102-14106. doi: 10.1039/c7dt03255b.

Authors

Jinjie Qian¹, Qipeng Li, Linfeng Liang, Ting-Ting Li, Yue Hu, Shaoming Huang

Affiliation

¹ College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China. jinjieqian@wzu.edu.cn yuehu@wzu.edu.cn smhuang@wzu.edu.cn.

PMID: 29022988
DOI: 10.1039/c7dt03255b

Abstract

A robust indium-organic framework (InOF-15) with open metal sites and Lewis basic sites has been successfully synthesized using a quinoline-based dicarboxylic acid. Moreover, it exhibits high IAST selective CO₂ sorption from CO₂/CH₄ and CO₂/N₂ mixtures at 273 K, which has been attributed to the coexistence of OMSs and LBSs with strong synergistic effects.