Hybrid a-CNH+TiO2+TiN-type surface layers produced on NiTi shape memory alloy for cardiovascular applications

Nanomedicine (Lond). 2017 Sep;12(18):2233-2244. doi: 10.2217/nnm-2017-0092. Epub 2017 Aug 18.

Abstract

Aim: The goal was to improve the properties of NiTi shape memory alloy to make it suitable for cardiac applications. For this purpose, a hybrid a-CNH+TiO2+TiN-type surface layer was produced on NiTi alloy and characterized.

Materials & methods: The NiTi alloy subjected to hybrid process combining low-temperature oxynitriding under glow discharge conditions and radio frequency chemical vapor deposition process was examined for microstructure, surface topography, corrosion resistance, wettability and surface-free energy, Ni ion release and platelets adhesion, aggregation and activation.

Results: The hybrid surface layers showed slightly increased surface roughness, better corrosion resistance, a more hydrophobic nature, decreased surface free energy, smaller release of nickel ions and reduced platelets activation.

Conclusion: The produced layers could expand the range of NiTi medical applications.

Keywords: NiTi alloy; glow discharge oxynitriding; radio frequency chemical vapor deposition process.

MeSH terms

  • Alloys
  • Biocompatible Materials
  • Blood Platelets / physiology
  • Cardiovascular Diseases / therapy*
  • Cell Adhesion
  • Corrosion
  • Electrochemical Techniques / methods
  • Hydrophobic and Hydrophilic Interactions
  • Materials Testing
  • Nickel / chemistry*
  • Platelet Activation
  • Platelet Aggregation
  • Prostheses and Implants
  • Surface Properties
  • Thermodynamics
  • Titanium / chemistry*
  • Wettability

Substances

  • Alloys
  • Biocompatible Materials
  • titanium nickelide
  • titanium dioxide
  • titanium nitride
  • Nickel
  • Titanium