Morphology and phase transformation from NaCaSiO3OH to Na2Ca2Si2O7 and photoluminescence evolution via Eu3+/Tb3+ doping

Mingyue Chen; Zhiguo Xia; Maxim S Molokeev; Qiulin Liu

doi:10.1039/c6cc06375f

Morphology and phase transformation from NaCaSiO₃OH to Na₂Ca₂Si₂O₇ and photoluminescence evolution via Eu³⁺/Tb³⁺ doping

Chem Commun (Camb). 2016 Sep 13;52(75):11292-11295. doi: 10.1039/c6cc06375f.

Authors

Mingyue Chen¹, Zhiguo Xia¹, Maxim S Molokeev², Qiulin Liu¹

Affiliations

¹ School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing 100083, China. xiazg@ustb.edu.cn.
² Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk 660036, Russia and Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russia.

PMID: 27711310
DOI: 10.1039/c6cc06375f

Abstract

A facile and controllable ethanol/water aided hydrothermal process was developed to prepare the NaCaSiO₃OH:Tb³⁺/Eu³⁺ phosphor. The morphologies were in situ constructed with the phase transformation from NaCaSiO₃OH to Na₂Ca₂Si₂O₇, and the intrinsic crystal structural transformation mechanism and the dependence of their photoluminescence tuning on the Tb³⁺/Eu³⁺ ratio have been discussed.