Two-Photon Tracer for Human Epidermal Growth Factor Receptor-2: Detection of Breast Cancer in a Live Tissue

Anal Chem. 2016 Oct 4;88(19):9412-9418. doi: 10.1021/acs.analchem.6b00912. Epub 2016 Sep 20.

Abstract

We have developed a two-photon fluorescent tracer (Pyr-affibody) that shows high selectivity for human epidermal growth factor receptor-2 (HER-2). Pyr-affibody showed absorption and emission maxima at 439 and 574 nm, respectively, with a two-photon absorption cross-section value of 40 × 10-50 cm4s/photon (GM) at 750 nm in aqueous buffer solution. The effective two-photon action cross-section value measured in HeLa cells was 600 GM at 730 nm, a value sufficient to obtain bright two-photon microscopy (TPM) images. Using Pyr-affibody, it was possible to detect HER-2 overexpressing cells and breast cancers at a depth of 90-130 μm in live mouse tissue by TPM.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Benzofurans / chemical synthesis
  • Benzofurans / pharmacology*
  • Benzofurans / radiation effects
  • Breast Neoplasms / diagnostic imaging*
  • Cell Line, Tumor
  • Fluorescent Dyes / chemical synthesis
  • Fluorescent Dyes / pharmacology*
  • Fluorescent Dyes / radiation effects
  • Humans
  • Light
  • Mice, Inbred BALB C
  • Pyrazines / chemical synthesis
  • Pyrazines / pharmacology*
  • Pyrazines / radiation effects
  • Receptor, ErbB-2 / metabolism*
  • Recombinant Fusion Proteins / chemical synthesis
  • Recombinant Fusion Proteins / pharmacology*
  • Recombinant Fusion Proteins / radiation effects

Substances

  • Benzofurans
  • Fluorescent Dyes
  • Pyrazines
  • Recombinant Fusion Proteins
  • ERBB2 protein, human
  • Receptor, ErbB-2