Atmospheric S and N deposition relates to increasing riverine transport of S and N in southwest China: Implications for soil acidification

Abstract

Following Europe and North America, East Asia has become a global hotspot for acid deposition, with very high deposition of both sulfur (S) and nitrogen (N) occurring in large areas of southwest and southeast China. This study shows that the outflow flux of sulfate (SO₄^2-) in three major tributaries of the Upper Yangtze River in the Sichuan Basin in southwest China has been increasing over the last three decades, which implies the regional soil acidification caused by increasing sulfur dioxide (SO₂) emissions. Since 2005, the outflow of SO₄^2- to the Upper Yangtze River from the Sichuan Basin has even reached the atmospheric SO₂ emission from the basin. In contrast to S emissions, the rapid increase in nitrogen (N) emissions, including nitrogen oxides (NOx) and ammonia (NH₃), have resulted in only a slight increase in nitrate (NO₃^-) concentrations in surface waters, indicating a large retention of N in the basin. Although N deposition currently contributes much less than S to soil acidification in this area, it is possible that catchments receiving a high input of N may be unable to retain a large fraction of the N deposition over long periods.

Keywords: Acidification; N saturation; Nitrogen budget; Sulfate adsorption; Sulfur budget.