TW-01, a piperazinedione-derived compound, inhibits Ras-mediated cell proliferation and angioplasty-induced vascular restenosis

Toxicol Appl Pharmacol. 2016 Aug 15:305:194-202. doi: 10.1016/j.taap.2016.06.013. Epub 2016 Jun 14.

Abstract

Purpose: Vascular smooth muscle cell (VSMC) proliferation plays a critical role in the pathogenesis of atherosclerosis and restenosis. This study investigated piperazinedione derived compound TW-01-mediated inhibitory effects on VSMC proliferation and intimal hyperplasia.

Methods: Cell proliferation was determined using [(3)H]-thymidine incorporation and MTT assay; cell cycle distribution was measured using flow cytometry; proteins and mRNA expression were determined using western blotting and RT-PCR analyses; DNA binding activity of nuclear factor-κB (NF-κB), as measured using enzyme-linked immunosorbent assays (ELISA); in vivo effects of TW-01 were determined using balloon angioplasty in the rat.

Results: TW-01 significantly inhibited cell proliferation. At the concentrations used, no cytotoxic effects were observed. Three predominant signaling pathways were inhibited by TW-01: (a) extracellular signal-regulated kinase (ERK)1/2 mitogen-activated protein kinase (MAPK) activation and its downstream effectors of c-fos, c-jun, and c-myc; (b) DNA binding activity of nuclear factor-κB (NF-κB); and, (c) Akt/protein kinase B (PKB) and cell cycle progression. Furthermore, TW-01 also inhibited Ras activation, a shared upstream event of each of these signaling cascades. In vascular injury studies, oral administration of TW-01 significantly suppressed intimal hyperplasia induced by balloon angioplasty.

Conclusion: The present study suggests that TW-01 might be a potential candidate for atherosclerosis treatment.

Keywords: Angioplasty; Atherosclerosis; Proliferation; Restenosis; TW-01; Vascular smooth muscle cell.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Angioplasty, Balloon / adverse effects*
  • Animals
  • Carotid Artery, Common / drug effects
  • Cell Proliferation / drug effects*
  • Cell Survival / drug effects
  • Cells, Cultured
  • Coronary Restenosis / drug therapy*
  • Cyclic AMP / metabolism
  • Cyclic GMP / metabolism
  • Diketopiperazines / pharmacology
  • Diketopiperazines / therapeutic use*
  • Human Umbilical Vein Endothelial Cells
  • Humans
  • Hyperplasia / drug therapy*
  • Male
  • Mitogen-Activated Protein Kinase 1 / metabolism
  • Mitogen-Activated Protein Kinase 3 / metabolism
  • Myocytes, Smooth Muscle / drug effects
  • Myocytes, Smooth Muscle / metabolism
  • Myocytes, Smooth Muscle / pathology
  • NF-kappa B / metabolism
  • Pyridines / pharmacology
  • Pyridines / therapeutic use*
  • Rats, Wistar
  • Tunica Intima / drug effects
  • Tunica Intima / pathology
  • ras Proteins / antagonists & inhibitors

Substances

  • Diketopiperazines
  • NF-kappa B
  • Pyridines
  • TW-01 compound
  • Cyclic AMP
  • Mitogen-Activated Protein Kinase 1
  • Mitogen-Activated Protein Kinase 3
  • ras Proteins
  • Cyclic GMP