Synthesis and controlled growth of osmium nanoparticles by electron irradiation

Dalton Trans. 2015 Dec 21;44(47):20308-11. doi: 10.1039/c5dt03205a. Epub 2015 Sep 29.

Abstract

We have synthesised osmium nanoparticles of defined size (1.5-50 nm) on a B- and S-doped turbostratic graphitic structure by electron-beam irradiation of an organometallic osmium complex encapsulated in self-spreading polymer micelles, and characterised them by transmission electron microscopy (TEM), high-resolution TEM (HRTEM), and atomic force microscopy (AFM) on the same grid. Oxidation of the osmium nanoparticles after exposure to air was detected by X-ray photoelectron spectroscopy (XPS).

Publication types

  • Research Support, Non-U.S. Gov't