A highly robust metal-organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4

Hongming He; Yang Song; Chuanqi Zhang; Fuxing Sun; Rongrong Yuan; Zheng Bian; Lianxun Gao; Guangshan Zhu

doi:10.1039/c5cc01281c

A highly robust metal-organic framework based on an aromatic 12-carboxyl ligand with highly selective adsorption of CO2 over CH4

Chem Commun (Camb). 2015 Jun 11;51(46):9463-6. doi: 10.1039/c5cc01281c.

Authors

Hongming He¹, Yang Song, Chuanqi Zhang, Fuxing Sun, Rongrong Yuan, Zheng Bian, Lianxun Gao, Guangshan Zhu

Affiliation

¹ State Key laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, China. fxsun@jlu.edu.cn.

PMID: 25959840
DOI: 10.1039/c5cc01281c

Abstract

A highly robust MOF based on a 12-carboxyl dendritic aromatic ligand and two Cd clusters is successfully synthesized. This activated MOF exhibits high heat of absorption of CO2 and highly selective adsorption of CO2 over CH4. Especially, a new type of topology (hhm-a) is presented.