Enhanced light emission from large-area monolayer MoS₂ using plasmonic nanodisc arrays

Nano Lett. 2015 Apr 8;15(4):2700-4. doi: 10.1021/acs.nanolett.5b00407. Epub 2015 Mar 5.

Abstract

Single-layer direct band gap semiconductors such as transition metal dichalcogenides are quite attractive for a wide range of electronics, photonics, and optoelectronics applications. Their monolayer thickness provides significant advantages in many applications such as field-effect transistors for high-performance electronics, sensor/detector applications, and flexible electronics. However, for optoelectronics and photonics applications, inherent monolayer thickness poses a significant challenge for the interaction of light with the material, which therefore results in poor light emission and absorption behavior. Here, we demonstrate enhanced light emission from large-area monolayer MoS2 using plasmonic silver nanodisc arrays, where enhanced photoluminescence up to 12-times has been measured. Observed phenomena stem from the fact that plasmonic resonance couples to both excitation and emission fields and thus boosts the light-matter interaction at the nanoscale. Reported results allow us to engineer light-matter interactions in two-dimensional materials and could enable highly efficient photodetectors, sensors, and photovoltaic devices, where photon absorption and emission efficiency highly dictate the device performance.

Keywords: 2D materials; CVD synthesis; LSPR; MoS2; photoluminescence.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Disulfides / chemistry*
  • Disulfides / radiation effects
  • Light
  • Luminescent Measurements / methods*
  • Materials Testing
  • Metal Nanoparticles / chemistry*
  • Metal Nanoparticles / radiation effects
  • Molybdenum / chemistry*
  • Molybdenum / radiation effects
  • Scattering, Radiation
  • Surface Plasmon Resonance / methods*

Substances

  • Disulfides
  • Molybdenum
  • molybdenum disulfide