A rapid LC-MS/MS quantification of peramivir using a simple and inexpensive sample precipitation: application to PK

Bioanalysis. 2015;7(3):319-32. doi: 10.4155/bio.14.248.

Abstract

Aim: Peramivir is a newly approved selective neuraminidase inhibitor designed to inhibit influenza virus infection.

Methodology/results: We report a robust and sensitive method utilizing simple precipitation extraction with LC-MS/MS for the high-throughput quantification. Addition of 0.06 M of ammonium formate and 0.1% formic acid in mobile phase could help reduce the matrix effect. This method uses 100 µl of plasma and covers a linear concentration range from 5 to 10,000 ng/ml. Other validation parameters are also evaluated and meet regulatory expectations by US FDA guidelines.

Conclusion: The developed HPLC-MS/MS method has been successfully applied to support a clinical pharmacokinetic study. The strategy presented here can be applied elsewhere and may be useful for other amphiphilic drugs.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Acids, Carbocyclic
  • Adult
  • Analytic Sample Preparation Methods / economics*
  • Chemical Precipitation*
  • Chromatography, Liquid
  • Cyclopentanes / analysis*
  • Cyclopentanes / blood
  • Cyclopentanes / isolation & purification*
  • Cyclopentanes / pharmacokinetics
  • Guanidines / analysis*
  • Guanidines / blood
  • Guanidines / isolation & purification*
  • Guanidines / pharmacokinetics
  • Humans
  • Male
  • Tandem Mass Spectrometry*
  • Time Factors

Substances

  • Acids, Carbocyclic
  • Cyclopentanes
  • Guanidines
  • peramivir