Soluble epoxide hydrolase as an anti-inflammatory target of the thrombolytic stroke drug SMTP-7

J Biol Chem. 2014 Dec 26;289(52):35826-38. doi: 10.1074/jbc.M114.588087. Epub 2014 Oct 31.

Abstract

Although ischemic stroke is a major cause of death and disability worldwide, only a small fraction of patients benefit from the current thrombolytic therapy due to a risk of cerebral hemorrhage caused by inflammation. Thus, the development of a new strategy to combat inflammation during thrombolysis is an urgent demand. The small molecule thrombolytic SMTP-7 effectively treats ischemic stroke in several animal models with reducing cerebral hemorrhage. Here we revealed that SMTP-7 targeted soluble epoxide hydrolase (sEH) to suppress inflammation. SMTP-7 inhibited both of the two sEH enzyme activities: epoxide hydrolase (which inactivates anti-inflammatory epoxy-fatty acids) and lipid phosphate phosphatase. SMTP-7 suppressed epoxy-fatty acid hydrolysis in HepG2 cells in culture, implicating the sEH inhibition in the anti-inflammatory mechanism. The sEH inhibition by SMTP-7 was independent of its thrombolytic activity. The simultaneous targeting of thrombolysis and sEH by a single molecule is a promising strategy to revolutionize the current stroke therapy.

Keywords: Enzyme Inhibitor; Enzyme Kinetics; Inflammation; Proteolysis; Stroke.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Animals
  • Anti-Inflammatory Agents / pharmacology*
  • Benzopyrans / pharmacology*
  • Colitis, Ulcerative / drug therapy
  • Colitis, Ulcerative / enzymology
  • Crohn Disease / drug therapy
  • Crohn Disease / enzymology
  • Epoxide Hydrolases / antagonists & inhibitors*
  • Epoxide Hydrolases / blood
  • Epoxide Hydrolases / chemistry
  • Fibrinolytic Agents / pharmacology*
  • Guillain-Barre Syndrome / drug therapy
  • Guillain-Barre Syndrome / enzymology
  • Hep G2 Cells
  • Humans
  • Kinetics
  • Male
  • Mice, Inbred C57BL
  • Molecular Sequence Data
  • Plasminogen / metabolism
  • Pyrrolidinones / pharmacology*
  • Rats, Inbred Lew

Substances

  • Anti-Inflammatory Agents
  • Benzopyrans
  • Fibrinolytic Agents
  • Pyrrolidinones
  • SMTP 7
  • Plasminogen
  • Epoxide Hydrolases