Crystal structure of (E)-N-(3,4-di-meth-oxy-benzyl-idene)morpholin-4-amine

Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 1;70(Pt 9):o935. doi: 10.1107/S160053681401678X. eCollection 2014 Sep 1.

Abstract

In the title compound, C13H18N2O3, the benzene ring makes a dihedral angle of 17.19 (11)° with the least-squares plane formed by the four C atoms of the morpholine ring, which adopts a chair conformation. In the crystal, C-H⋯N hydrogen bonds link the mol-ecules into supramolecular chains running along a 21 screw axis parallel to the b-axis direction. Weak C-H⋯π inter-actions are also observed.

Keywords: C—H⋯π inter­actions; Schiff bases; crystal structure; hydrogen bonding; morpholin-4-amine.