Molecular genetic characterization of terreic acid pathway in Aspergillus terreus

Org Lett. 2014 Oct 17;16(20):5250-3. doi: 10.1021/ol502242a. Epub 2014 Sep 29.

Abstract

Terreic acid is a natural product derived from 6-methylsalicylic acid (6-MSA). A compact gene cluster for its biosynthesis was characterized. Isolation of the intermediates and shunt products from the mutant strains, combined with bioinformatic analyses, allowed for the proposition of a biosynthetic pathway for terreic acid.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Aspergillus / chemistry*
  • Aspergillus / genetics
  • Biological Products / chemistry
  • Biological Products / metabolism*
  • Biological Products / pharmacology
  • Biosynthetic Pathways / genetics
  • Molecular Structure
  • Multigene Family*
  • Quinones / chemistry
  • Quinones / metabolism
  • Quinones / pharmacology
  • Salicylates / chemistry
  • Salicylates / metabolism

Substances

  • Biological Products
  • Quinones
  • Salicylates
  • 6-methylsalicylic acid
  • terreic acid