X-ray photoemission study of CeTIn(5) (T = Co, Rh, Ir)

J Phys Condens Matter. 2014 May 21;26(20):205601. doi: 10.1088/0953-8984/26/20/205601. Epub 2014 May 1.

Abstract

We investigated CeTIn5 (T = Co, Rh, Ir) using temperature- and angle-dependent x-ray photoemission spectroscopy. The Ce 3d core level has a very similar shape for all three materials and is indicative of weak f-hybridization. The spectra were analyzed using a simplified version of the Anderson impurity model, which yields a Ce 4f occupancy that is larger than 0.9. The temperature dependence shows a continuous, irreversible and exclusive broadening of the Ce 3d peaks, due to oxidation of Ce at the surface.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Alloys / chemistry
  • Computer Simulation
  • Electric Conductivity
  • Metals / chemistry*
  • Models, Chemical*
  • Models, Molecular*
  • Photoelectron Spectroscopy / methods*

Substances

  • Alloys
  • Metals