Therapeutic use of H2O2-responsive anti-oxidant polymer nanoparticles for doxorubicin-induced cardiomyopathy

Biomaterials. 2014 Jul;35(22):5944-53. doi: 10.1016/j.biomaterials.2014.03.084. Epub 2014 Apr 22.

Abstract

Doxorubicin (DOX) is a commonly used anti-neoplastic agent but its clinical use is limited due to serious hepatic and cardiac side effects. DOX-induced toxicity is mainly associated with overproduction of reactive species oxygen (ROS) such as hydrogen peroxide (H2O2). We have recently developed H2O2-responsive anti-oxidant polymer, polyoxalate containing vanillyl alcohol (PVAX), which is designed to rapidly scavenge H2O2 and release vanillyl alcohol with anti-oxidant, anti-inflammatory and anti-apoptotic properties. In this study, we report that PVAX nanoparticles are novel therapeutic agents for treating DOX-induced cardiac and hepatic toxicity. Intraperitoneal injection of PVAX nanoparticles (4 mg/kg/day) resulted in significant inhibition in apoptosis in liver and heart of DOX-treated mice by suppressing the activation of poly (ADP ribose) polymerase 1 (PARP-1) and caspase-3. PVAX treatment also prevented DOX-induced cardiac dysfunction. Furthermore, survival rate (vehicle = 35% vs. PVAX = 75%; p < 0.05) was significantly improved in a PVAX nanoparticles-treated group compared with vehicle treated groups. Taken together, we anticipate that PVAX nanoparticles could be a highly specific and potent treatment modality in DOX-induced cardiac and hepatic toxicity.

Keywords: Anti-oxidant; Doxorubicin; Heart failure; Hydrogen peroxide; Polyoxalate.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antioxidants / chemistry
  • Antioxidants / therapeutic use*
  • Benzyl Alcohols / chemistry
  • Benzyl Alcohols / therapeutic use
  • Cardiomyopathies / chemically induced
  • Cardiomyopathies / drug therapy*
  • Doxorubicin
  • Hydrogen Peroxide / metabolism*
  • Male
  • Mice
  • Mice, Inbred C57BL
  • Nanoparticles / chemistry
  • Nanoparticles / therapeutic use
  • Oxalic Acid / chemistry
  • Oxalic Acid / therapeutic use*
  • Polymers / chemistry
  • Polymers / therapeutic use*

Substances

  • Antioxidants
  • Benzyl Alcohols
  • Polymers
  • Doxorubicin
  • Oxalic Acid
  • Hydrogen Peroxide
  • vanillyl alcohol