Copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes

Org Lett. 2014 Jan 3;16(1):270-3. doi: 10.1021/ol403263c. Epub 2013 Dec 13.

Abstract

A novel and highly practical reaction for the copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes is presented here. This methodology provides a general and straightforward way to synthesize a variety of useful CF3-containing nitriles, which can be used for further preparation of pharmaceutically and agrochemically important compounds in synthetic organic chemistry.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Alkenes / chemistry*
  • Catalysis
  • Copper / chemistry*
  • Hydrocarbons, Fluorinated / chemical synthesis*
  • Hydrocarbons, Fluorinated / chemistry
  • Methylation
  • Molecular Structure
  • Nitriles / chemical synthesis*
  • Nitriles / chemistry
  • Organometallic Compounds / chemistry*

Substances

  • Alkenes
  • Hydrocarbons, Fluorinated
  • Nitriles
  • Organometallic Compounds
  • Copper