An intensely luminescent metal-organic framework based on a highly light-harvesting dyclo-metalated iridium(III) unit showing effective detection of explosives

Lina Li; Shuquan Zhang; Liangjin Xu; Liang Han; Zhong-Ning Chen; Junhua Luo

doi:10.1021/ic402158n

An intensely luminescent metal-organic framework based on a highly light-harvesting dyclo-metalated iridium(III) unit showing effective detection of explosives

Inorg Chem. 2013 Nov 4;52(21):12323-5. doi: 10.1021/ic402158n. Epub 2013 Oct 21.

Authors

Lina Li¹, Shuquan Zhang, Liangjin Xu, Liang Han, Zhong-Ning Chen, Junhua Luo

Affiliation

¹ Key Laboratory of Optoelectronic Materials Chemistry and Physics, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences , Fuzhou 350002, China.

PMID: 24144427
DOI: 10.1021/ic402158n

Abstract

An intense visible yellow-orange emission with long lifetime and enhanced quantum yield has been achieved for a metal-organic framework based on a highly light-harvesting dyclo-metalated iridium(III) unit, which shows effective detection of nitroaromatic explosives on the ppm scale.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Explosive Agents / analysis*
Iridium / chemistry*
Light
Luminescent Measurements / methods*
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry
Spectrophotometry, Ultraviolet

Substances

Explosive Agents
Organometallic Compounds
Iridium