12-(2-Hy-droxy-6-oxo-cyclo-hex-1-en-yl)-9,10-di-hydro-8H-benzo[a]xanthen-11(12H)-one

Acta Crystallogr Sect E Struct Rep Online. 2013 Sep 18;69(Pt 10):o1558-9. doi: 10.1107/S1600536813025324. eCollection 2013.

Abstract

In the xanthenone system of the title compound, C23H20O4, the pyran ring has a maximum deviation of 0.111 (1) Å from planarity and the outer cyclo-hexene ring exhibits a puckered conformation. The three methyl-ene C atoms of the cyclo-hexene ring bonded to the pyran unit are disordered over two sets of sites [occupancies = 0.570 (3) and 0.430 (3)]. In the crystal, mol-ecules are linked by C-H⋯O and O-H⋯O hydrogen bonds, forming a two-dimensional network parallel to (110). A C-H⋯π inter-action occurs between these networks.