Abstract
Gold(I)-catalyzed allene-vinylcyclopropane cycloisomerization leads to the tricyclic framework of the protoilludanes in a single step by a reaction that involves a cyclopropane ring expansion and a Prins cyclization.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkadienes / chemistry
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Biological Products / chemical synthesis*
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Biological Products / chemistry
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Catalysis
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Cyclization
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Cyclopropanes / chemistry
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Gold / chemistry*
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Isomerism
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Molecular Structure
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Polycyclic Sesquiterpenes
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Sesquiterpenes / chemical synthesis*
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Sesquiterpenes / chemistry
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Vinyl Compounds / chemistry
Substances
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Alkadienes
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Biological Products
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Cyclopropanes
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Polycyclic Sesquiterpenes
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Sesquiterpenes
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Vinyl Compounds
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protoilludane
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propadiene
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Gold