Development of a practical, asymmetric synthesis of the hepatitis C virus protease inhibitor MK-5172

Org Lett. 2013 Aug 16;15(16):4174-7. doi: 10.1021/ol401864t. Epub 2013 Aug 6.

Abstract

The development of a practical, asymmetric synthesis of the hepatitis C virus (HCV) protease inhibitor MK-5172 (1), an 18-membered macrocycle, is described.

MeSH terms

  • Amides
  • Antiviral Agents / chemical synthesis*
  • Antiviral Agents / chemistry
  • Antiviral Agents / pharmacology*
  • Carbamates
  • Cyclopropanes
  • Hepacivirus / drug effects*
  • Macrocyclic Compounds / chemical synthesis*
  • Macrocyclic Compounds / chemistry
  • Macrocyclic Compounds / pharmacology*
  • Molecular Structure
  • Protease Inhibitors / chemical synthesis*
  • Protease Inhibitors / chemistry
  • Protease Inhibitors / pharmacology*
  • Quinoxalines / chemical synthesis*
  • Quinoxalines / chemistry
  • Quinoxalines / pharmacology*
  • Sulfonamides

Substances

  • Amides
  • Antiviral Agents
  • Carbamates
  • Cyclopropanes
  • Macrocyclic Compounds
  • Protease Inhibitors
  • Quinoxalines
  • Sulfonamides
  • grazoprevir