Encapsulation of clay within polymer particles in a high-solids content aqueous dispersion

Langmuir. 2013 Aug 6;29(31):9849-56. doi: 10.1021/la401301s. Epub 2013 Jul 24.

Abstract

By using a two-step polymerization process, it was possible to encapsulate clay platelets within polymer particles dispersed in water. First, seed polymer particles with chemically bonded clay were obtained by batch miniemulsion polymerization. Then, the clay was buried within the particles by the addition of neat monomer in a second step. The final stable dispersions can have a solids content of up to 50 wt %. Transmission electron microscopy images clearly show the presence of clay platelets inside the polymer colloids, although they are not totally exfoliated. The obtained nanocomposites showed an increase in both the storage modulus in the rubbery state and the water resistance as the clay content increases. The approach presented here might be useful for encapsulating other high-aspect ratio nanofillers.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aluminum Silicates / chemistry*
  • Clay
  • Particle Size
  • Polymerization
  • Polymers / chemical synthesis
  • Polymers / chemistry*
  • Surface Properties
  • Water / chemistry

Substances

  • Aluminum Silicates
  • Polymers
  • Water
  • Clay