Combined coagulation-flocculation and sequencing batch reactor with phosphorus adjustment for the treatment of high-strength landfill leachate: experimental kinetics and chemical oxygen demand fractionation

J Air Waste Manag Assoc. 2013 May;63(5):591-604. doi: 10.1080/10962247.2013.775086.

Abstract

The treatability of high-strength landfill leachate is challenging and relatively limited. This study examines the feasibility of treating high-strength landfill leachate (chemical oxygen demand [COD]: 7,760-11,770 mg/L, biochemical oxygen demand [BOD5]: 2,760-3,569 mg/L, total nitrogen [TN] = 980-1,160 mg/L) using a sequencing batch reactor (SBR) preceded by a coagulation-flocculation process with phosphorus nutritional balance under various mixing and aeration patterns. Simulations were also conducted to define kinetic parameters and COD fractionation. Removal efficiencies reached 89% for BOD5, 60% for COD, and 72% for TN, similar to and better than reported studies, albeit with a relatively lower hydraulic retention time (HRT) and solid retention time (SRT). The coupled experimental and simulation results contribute in filling a gap toward managing high-strength landfill leachate and providing guidelines for corresponding SBR applications.

Implications: The treatability of high-strength landfill leachate, which is challenging and relatively limited, was demonstrated using a combined coagulation-flocculation with SBR technology and nutrient balance adjustment. The most suitable coagulant, kinetic design parameters, and COD fractionation were defined using coupled experimental and simulation results contributing in filling a gap toward managing high-strength leachate by providing guidelines for corresponding SBR applications and anticipating potential constraints related to the non-biodegradable COD fraction. In this context, while the combined coagulation-flocculation and SBR process improved removal efficiencies, posttreatment may be required for high-strength leachate, depending on discharge standards and ultimate usage of the treated leachate.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Biological Oxygen Demand Analysis
  • Bioreactors*
  • Chemical Fractionation
  • Flocculation
  • Kinetics
  • Phosphorus / chemistry*
  • Refuse Disposal / methods*
  • Water Pollutants, Chemical / chemistry*

Substances

  • Water Pollutants, Chemical
  • Phosphorus