Anion-dependent self-assembly of near-infrared luminescent 24- and 32-metal Cd-Ln complexes with drum-like architectures

J Am Chem Soc. 2013 Jun 12;135(23):8468-71. doi: 10.1021/ja4031243. Epub 2013 Jun 3.

Abstract

Two series of 4d-4f clusters [Ln8Cd24L12(OAc)48] and [Ln6Cd18L9Cl8(10)(OAc)28(26)] (Ln = Nd, Gd, Er, and Yb) with novel drum-like structures were prepared using a flexible Schiff base ligand. Their NIR luminescence properties were determined.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Anions / chemistry
  • Cadmium / chemistry*
  • Lanthanoid Series Elements / chemistry*
  • Luminescence*
  • Models, Molecular
  • Molecular Structure
  • Organometallic Compounds / chemistry*
  • Schiff Bases / chemistry*
  • Spectroscopy, Near-Infrared

Substances

  • Anions
  • Lanthanoid Series Elements
  • Organometallic Compounds
  • Schiff Bases
  • Cadmium