Electrochemical disinfection of fish pathogens in seawater without the production of a lethal concentration of chlorine using a flow reactor

J Biosci Bioeng. 2013 Oct;116(4):480-4. doi: 10.1016/j.jbiosc.2013.04.013. Epub 2013 May 4.

Abstract

An electrochemical disinfection system employing a honeycombed platinum coated titanium electrode was developed for the disinfection of seawater. Cell suspensions (2 l, 10³ cells/ml) of the fish pathogens, Vibrio alginolyticus, Edwardsiella tarda, Lactococcus garvieae and Vibrio anguillarum were circulated in a reactor equipped with 10 sets of these electrodes at a flow rate of 200 ml/min with an applied potential of 1.0 V vs. Ag/AgCl reference electrode. The circulated cells were completely disinfected after 3 h of treatment, whereas free residual chlorine generated due to seawater electrolysis was below 0.1 ppm. In addition, a diphenyl-1-pyrenylphosphine fluorescent assay revealed that lipid peroxidation in the cell membranes of disinfected bacteria was induced probably by reactive oxygen species generated during electrochemical treatment.

Keywords: Disinfection byproducts; Electrochemical disinfection; Flow reactor; Lipid peroxidation; Marine pathogen.

MeSH terms

  • Animals
  • Cell Membrane / pathology
  • Chlorine / analysis*
  • Chlorine / toxicity
  • Disinfection / instrumentation*
  • Disinfection / methods*
  • Electrodes
  • Electrolysis / instrumentation*
  • Electrolysis / methods*
  • Fishes / microbiology*
  • Fluorescent Dyes / analysis
  • Lipid Peroxidation
  • Organophosphorus Compounds / analysis
  • Pyrenes / analysis
  • Reactive Oxygen Species / metabolism
  • Seawater / microbiology*
  • Time Factors
  • Titanium

Substances

  • Fluorescent Dyes
  • Organophosphorus Compounds
  • Pyrenes
  • Reactive Oxygen Species
  • diphenyl-1-pyrenylphosphine
  • Chlorine
  • Titanium