Concise synthetic routes to human insulin

Org Lett. 2013 Feb 15;15(4):960-3. doi: 10.1021/ol400149j. Epub 2013 Feb 7.

Abstract

We report a set of concise and efficient routes for the chemical synthesis of human insulin using a two- or three-step combination procedure that employs Trt, Acm, and t-Bu cysteine protection schemes. Starting with resin-bound assembled A and B chains, human insulin can be obtained within the span of a single work day in 5.4% overall yield based on the crude A or B chain.

MeSH terms

  • Amino Acid Sequence
  • Chromatography, High Pressure Liquid
  • Cysteine / chemistry
  • Disulfides
  • Humans
  • Insulin / chemical synthesis*
  • Insulin / chemistry

Substances

  • Disulfides
  • Insulin
  • Cysteine