Shape selective plate-form Ga(2)O(3) with strong metal-support interaction to overlying Pd for hydrogenation of CO(2) to CH(3)OH

Xiwen Zhou; Jin Qu; Feng Xu; Jingping Hu; John S Foord; Ziyan Zeng; Xinlin Hong; Shik Chi Edman Tsang

doi:10.1039/c3cc38455a

Shape selective plate-form Ga(2)O(3) with strong metal-support interaction to overlying Pd for hydrogenation of CO(2) to CH(3)OH

Chem Commun (Camb). 2013 Feb 28;49(17):1747-9. doi: 10.1039/c3cc38455a.

Authors

Xiwen Zhou¹, Jin Qu, Feng Xu, Jingping Hu, John S Foord, Ziyan Zeng, Xinlin Hong, Shik Chi Edman Tsang

Affiliation

¹ Wolfson Catalysis Centre, Department of Chemistry, University of Oxford, Oxford, OX1 3QR, UK.

PMID: 23340904
DOI: 10.1039/c3cc38455a

Abstract

A stronger metal-support interaction between Pd and plate-form Ga(2)O(3) nanocrystals covered with the predominant 002 surface than other Ga(2)O(3) surfaces is found, which gives higher methanol yield in catalytic CO(2) hydrogenation.