Abstract
A μ(4)-Cl bridged anionic sodalite-type porous metal-organic framework (Et(2)NH(2))(3)[(Cu(4)Cl)(3)(TTCA)(8)]·26DEF was synthesized, in which Et(2)NH(2)(+) can be exchanged by Li(+) cations. The results of gas measurements indicate that Et(2)NH(2)(+) and Li(+) are beneficial for methane and hydrogen storage, respectively.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Cations / chemistry
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Hydrogen / chemistry*
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Methane / chemistry*
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Models, Molecular
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Organometallic Compounds / chemical synthesis
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Organometallic Compounds / chemistry*
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Porosity
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Surface Properties
Substances
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Cations
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Organometallic Compounds
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Hydrogen
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Methane