Abstract
A small library of chiral imidate-ferrocenylphosphane ligands was efficiently synthesized (8 examples) and evaluated in the iridium(I)-catalyzed hydrogenation of unfunctionalized and poorly functionalized olefins. These catalysts perform very well in a range of examples (yields and ee's up to 100%).
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Alkenes / chemistry*
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Catalysis
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Ferrous Compounds / chemical synthesis
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Ferrous Compounds / chemistry*
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Hydrogenation
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Imidoesters / chemical synthesis
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Imidoesters / chemistry*
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Iridium / chemistry*
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Ligands
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Metallocenes
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Phosphines / chemical synthesis
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Phosphines / chemistry*
Substances
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Alkenes
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Ferrous Compounds
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Imidoesters
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Ligands
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Metallocenes
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Phosphines
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Iridium
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phosphine
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ferrocene