Lack of the consensus sequence necessary for tryptophan prenylation in the ComX pheromone precursor

Biosci Biotechnol Biochem. 2012;76(8):1492-6. doi: 10.1271/bbb.120206. Epub 2012 Aug 7.

Abstract

ComX, an oligopeptide pheromone that stimulates the natural genetic competence controlled by quorum sensing in Bacillus subtilis and related bacilli, contains a prenyl-modified tryptophan residue. Since ComX is the only protein known to contain prenylated tryptophan, the universality of this unique posttranslational modification has yet to be determined. Recently, we developed a cell-free assay system in which the tryptophan residue in the ComX(RO-E-2) pheromone precursor derived from B. subtilis strain RO-E-2 can be geranylated by the ComQ(RO-E-2) enzyme. We report here our attempt to identify the consensus sequence surrounding the geranylated tryptophan residue by using the cell-free system with various ComX(RO-E-2) pheromone precursor analogs. We found that [47-58]ComX(RO-E-2), corresponding to the C-terminal 12-residue peptide of the pheromone precursor, contained a short sequence essential for geranylation. We also found that the length of the sequence between the tryptophan residue and the C-terminus was important for geranylation, and that some [47-58]ComX(RO-E-2) pheromone precursor amino acids were involved in the geranylation reaction. However, we could not identify a consensus sequence surrounding the geranylated tryptophan. Our evidence suggests that, like Rab which lacks a consensus sequence yet is geranylgeranyl-modified on a cysteine residue, the ComX pheromone and its precursor also lack a consensus sequence.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amino Acid Sequence
  • Bacillus subtilis / genetics*
  • Bacillus subtilis / metabolism
  • Bacterial Proteins / genetics*
  • Bacterial Proteins / metabolism
  • Cell-Free System
  • Cloning, Molecular
  • Consensus Sequence
  • Escherichia coli / genetics
  • Genetic Fitness
  • Membrane Proteins / genetics
  • Membrane Proteins / metabolism
  • Molecular Sequence Data
  • Pheromones / genetics*
  • Pheromones / metabolism
  • Prenylation
  • Protein Isoforms / genetics
  • Protein Isoforms / metabolism
  • Protein Precursors / genetics
  • Protein Precursors / metabolism*
  • Protein Processing, Post-Translational / genetics*
  • Quorum Sensing / genetics
  • Tryptophan / metabolism

Substances

  • Bacterial Proteins
  • ComX protein, Bacillus subtilis
  • Membrane Proteins
  • Pheromones
  • Protein Isoforms
  • Protein Precursors
  • comQ protein, Bacillus subtilis
  • Tryptophan