Stepwise assembly of homochiral coordination polymers based on the precursor of an enantiopure Yb3Mn6 cluster

Dalton Trans. 2012 Sep 21;41(35):10518-20. doi: 10.1039/c2dt30667k. Epub 2012 Aug 1.

Abstract

Two homochiral coordination polymers, namely, [Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)(isonicotinate)(2)(HOMe)(2)][Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)(isonicotinate)(2)(HOMe)(4)](NO(3))(2)·6MeOH·12H(2)O (5) (H(3)L = (S,E)-4-(2-hydroxybenzylideneamino)-2-hydroxybutanoic acid) and [Yb(III)(3)Mn(III)(6)Na(L)(6)(μ(2)-OMe)(6)(OOCH)(3)]I·17H(2)O (6), have been constructed by utilizing a stable enantiopure [Yb(III)(3)Mn(III)(6)(L)(6)(μ(2)-OMe)(6)](3+) (Yb(3)Mn(6)) cluster as a precursor.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Crystallography, X-Ray
  • Ligands
  • Manganese / chemistry*
  • Molecular Conformation
  • Polymers / chemical synthesis
  • Polymers / chemistry*
  • Stereoisomerism
  • Temperature
  • Ytterbium / chemistry*

Substances

  • Ligands
  • Polymers
  • Manganese
  • Ytterbium