Antiangiogenic nanotherapy with lipase-labile Sn-2 fumagillin prodrug

Nanomedicine (Lond). 2012 Oct;7(10):1507-19. doi: 10.2217/nnm.12.27. Epub 2012 Jun 18.

Abstract

Background: The chemical instability of antiangiogenic fumagillin, combined with its poor retention during intravascular transit, requires an innovative solution for clinical translation. We hypothesized that an Sn-2 lipase-labile fumagillin prodrug, in combination with a contact-facilitated drug delivery mechanism, could be used to address these problems.

Methods: α(v)β(3)-targeted and nontargeted nanoparticles with and without fumagillin in the prodrug or native forms were evaluated in vitro and in vivo in the Matrigel™ (BD Biosciences, CA, USA) plug model of angiogenesis in mice.

Results: In vitro experiments demonstrated that the new fumagillin prodrug decreased viability at least as efficacious as the parent compound, on an equimolar basis. In the Matrigel mouse angiogenesis model, α(v)β(3)-fumagillin prodrug decreased angiogenesis as measured by MRI (3T), while the neovasculature was unaffected with the control nanoparticles.

Conclusion: The present approach resolved the previously intractable problems of drug instability and premature release in transit to target sites.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Biological Availability
  • Cells, Cultured
  • Cyclohexanes / pharmacokinetics
  • Cyclohexanes / therapeutic use*
  • Fatty Acids, Unsaturated / pharmacokinetics
  • Fatty Acids, Unsaturated / therapeutic use*
  • Humans
  • Lipase / therapeutic use*
  • Mice
  • Nanomedicine*
  • Neovascularization, Pathologic / therapy*
  • Prodrugs / therapeutic use*
  • Rats
  • Sesquiterpenes / pharmacokinetics
  • Sesquiterpenes / therapeutic use

Substances

  • Cyclohexanes
  • Fatty Acids, Unsaturated
  • Prodrugs
  • Sesquiterpenes
  • fumagillin
  • Lipase