Porphyrin-LEGO®: synthesis of a hexafullereno-diporphyrin using porphyrins programmed for [4+2]-cycloaddition

Chem Commun (Camb). 2012 May 7;48(36):4359-61. doi: 10.1039/c2cc31218b. Epub 2012 Mar 26.

Abstract

A hexafullereno-diporphyrinoid was obtained in a sequence of cycloaddition steps using porphyrins programmed for [4+2]-cycloaddition reactions and C(60)-fullerene.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemistry Techniques, Synthetic / methods*
  • Dimerization
  • Fullerenes / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Porphyrins / chemical synthesis*
  • Porphyrins / chemistry*
  • Sulfur Dioxide / chemistry

Substances

  • Fullerenes
  • Porphyrins
  • Sulfur Dioxide
  • fullerene C60