A new Schiff base based on vanillin and naphthalimide as a fluorescent probe for Ag+ in aqueous solution

Abstract

A new Schiff base based on vanillin and naphthalimide was designed and synthesized as fluorescent probe. The probe showed high selectivity for Ag(+) over other metal ions such as Pb(2+), Na(+), K(+), Cd(2+), Ba(2+), Cr(3+), Zn(2+), Cu(2+), Ni(2+), Ca(2+), Al(3+) and Mg(2+) in aqueous solution. A new fluorescence emission was observed at 682 nm in the presence of Ag(+) ion. The fluorescence intensity quenched with increasing the concentration of Ag(+) at 682 nm. The method of job's plot confirmed the 1:2 complex between Ag(+) and probe, and the mechanism was proposed.