An improved singlet oxygen sensitizer with two-photon absorption and emission in the biological transparency window as a result of ground state symmetry-breaking

Chem Commun (Camb). 2012 Feb 4;48(11):1689-91. doi: 10.1039/c2cc15904j. Epub 2011 Dec 19.

Abstract

A chromophore featuring a diyne bridge that connects two dibromobenzene moieties shows a much improved two-photon singlet oxygen generation ability in the biological transparency window compared to a related and relevant literature benchmark, as a result of a distorted ground state.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Absorption
  • Bromobenzenes / chemistry*
  • Photons*
  • Photosensitizing Agents / chemistry*
  • Singlet Oxygen / chemistry*

Substances

  • Bromobenzenes
  • Photosensitizing Agents
  • Singlet Oxygen