A multifunctional organic-inorganic hybrid structure based on Mn(III)-porphyrin and polyoxometalate as a highly effective dye scavenger and heterogenous catalyst

Chao Zou; Zhijuan Zhang; Xuan Xu; Qihan Gong; Jing Li; Chuan-De Wu

doi:10.1021/ja209196t

A multifunctional organic-inorganic hybrid structure based on Mn(III)-porphyrin and polyoxometalate as a highly effective dye scavenger and heterogenous catalyst

J Am Chem Soc. 2012 Jan 11;134(1):87-90. doi: 10.1021/ja209196t. Epub 2011 Dec 16.

Authors

Chao Zou¹, Zhijuan Zhang, Xuan Xu, Qihan Gong, Jing Li, Chuan-De Wu

Affiliation

¹ Department of Chemistry, Zhejiang University, Hangzhou 310027, PR China.

PMID: 22148189
DOI: 10.1021/ja209196t

Abstract

A two-step synthesis strategy has led to a unique layered polyoxometalate-Mn(III)-metalloporphyrin-based hybrid material. The hybrid solid demonstrates remarkable capability for scavenging of dyes and for heterogeneous selective oxidation of alkylbenzenes with excellent product yields and 100% selectivity.